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Monday, March 5, 2018

Hybrid Orbital



Hybridization was introduced to explain molecular structure when the valence bond theory failed to correctly predict them. It is experimentally observed that bond angles in organic compounds are close to 109o, 120o, or 180o. According to Valence Shell Electron Pair Repulsion (VSEPR) theory, electron pairs repel each other and the bonds and lone pairs around a central atom are generally separated by the largest possible angles. Carbon is a perfect example showing the need for hybrid orbital’s.
According to Valence Bond Theory, carbon should form two covalent bonds, resulting in a CH2, because it has two unpaired electrons in its electronic configuration. However, experiments have shown that CH2CH2 is highly reactive and cannot exist outside of a reaction. Therefore, this does not explain how CH4 can exist. To form four bonds the configuration of carbon must have four unpaired electrons. The only way CH4 it can be explained is, the 2s and the 3 2p orbitals fused together to make four, equal energy sp3 hybrid orbital’s. Now that carbon has four unpaired electrons it can have four equal energy bonds. The hybridization of orbitals is also greatly favored because hybridized orbitals are lower in energy compared to their separated, hybridized counterparts. This results in more stable compounds when hybridization occurs. Also, major parts of the hybridized orbitals, or the frontal lobes, overlap better than the lobes of hybridized orbitals. This leads to better bonding.  
The next topics will explain the various types of hybridization and how each type helps explain the structure of certain molecules.
sp3 hybridization
sp3 hybridization can explain the tetrahedral structure of molecules. In it, the 2s orbitals and all three of the 2p orbitals hybridize to form four sp orbitals, each consisting of 75% p character and 25% s character. The frontal lobes align themselves in the manner shown below. In this structure, electron repulsion is minimized.
Hybridization of an s orbital with all three p orbital results in four sp3 hybrid orbitals. sp3 hybrid orbitals are oriented at bond angle of 109.5o from each other. This 109.5oarrangement gives tetrahedral geometry (Figure 4).

Example: sp3 Hybridization in Methane
Because carbon plays such a significant role in organic chemistry, we will be using it
as an example here. Carbon's 2s and all three of its 3p orbitals hybridize to form four sp3 orbitals.
These orbitals then bond with four hydrogen atoms through sp3-s orbital overlap, creating methane.
 The resulting shape is tetrahedral, since that minimizes electron repulsion.
Hybridization


Lone Pairs: Remember to take into account lone pairs of electrons.
These lone pairs cannot double bond so they are placed in their own hybrid orbital.
This is why H2O is tetrahedral.
 We can also build sp3d and sp3d2 hybrid orbitals if we go beyond s and p sub-shells.
sp2 hybridization
sp2 hybridization can explain the trigonal planar structure of molecules. In it, the 2s orbitals and two of the 2p orbitals hybridize to form three sp orbitals, each consisting of 67% p and 33% s character. The frontal lobes align themselves in the trigonal planar structure, pointing to the corners of a triangle in order to minimize electron repulsion and to improve overlap. The remaining p orbital remains unchanged and is perpendicular to the plane of the three sp2 orbitals.


 figure3.gif

Example: sp2 Hybridization in Aluminum Trihydride
In aluminum trihydride, one 2s orbital and two 2p orbitals hybridize to
form three sp2 orbitals that align themselves in the trigonal planar structure.
The three Al sp2 orbitals bond with with 1s orbitals from the three hydrogens
through sp2-s orbital overlap.

Example: sp2 Hybridization in Ethene
Similar hybridization occurs in each carbon of ethene. For each carbon, one 2s orbital
and two 2p orbitals hybridize to form three sp2 orbitals. These hybridized orbitals align
themselves in the trigonal planar structure. For each carbon, two of these sp orbitals
bond with two 1s hydrogen orbitals through s-sp orbital overlap. The remaining sp2 orbitals
on each carbon are bonded with each other, forming a bond between each carbon through
sp2-sp2 orbital overlap. This leaves us with the two p orbitals on each carbon that
have a single carbon in them. These orbitals form a ? bonds through p-p orbital
overlap, creating a double bond between the two carbons. Because a double bond
was created, the overall structure of the ethene compound is linear. However,
the structure of each molecule in ethene, the two carbons, is still trigonal planar.
sp Hybridization
sp Hybridization can explain the linear structure in molecules. In it, the 2s orbital and one of the 2p orbitals hybridize to form two sp orbitals, each consisting of 50% s and 50% p character. The front lobes face away from each other and form a straight line leaving a 180° angle between the two orbitals. This formation minimizes electron repulsion. Because only one p orbital was used, we are left with two unaltered 2p orbitals that the atom can use. These p orbitals are at right angles to one another and to the line formed by the two sp orbitals.
These p orbital’s come into play in compounds such as ethyne where they form two addition? bonds, resulting in in a triple bond. This only happens when two atoms, such as two carbons, both have two p orbitals that each contain an electron. An sp hybrid orbital results when an s orbital is combined with p orbital (Figure 2). We will get two sp hybrid orbitals since we started with two orbitals (s and p). sp hybridization results in a pair of directional sp hybrid orbitals pointed in opposite directions. These hybridized orbitals result in higher electron density in the bonding region for a sigma bond toward the left of the atom and for another sigma bond toward the right. In addition, sp hybridization provides linear geometry with a bond angle of 180o.

Example: sp Hybridization in Magnesium Hydride
In magnesium hydride, the 3s orbital and one of the 3p orbitals from magnesium
Hybridize to form two sp orbitals. The two frontal lobes of the sp orbitals face away from
Each other forming a straight line leading to a linear structure. These two sp orbitals bond
With the two 1s orbitals of the two hydrogen atoms through sp-s orbital overlap.
Hybridization

An easy way to figure out what hybridization an atom has is to just count the number of atoms bonded to it and the number of lone pairs. Double and triple bonds still count as being only bonded to one atom. Use this method to go over the above problems again and make sure we understand it. It's a lot easier to figure out the hybridization this way.

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